determination of trace amounts of lead by modified graphite furnace atomic absorption spectrometry after liquid phase microextraction with pyrimidine-2-thiol测定微量铅的改性后的石墨炉原子吸收光谱法与pyrimidine-2-thiol液相微萃取.pdfVIP

American Journal of Analytical Chemistry , 2011, 2, 757-767 doi:10.4236/ajac.2011.27087 Published Online November 2011 (http://www.SciRP.org/journal/ajac) Determination of Trace Amounts of Lead by Modified Graphite Furnace Atomic Absorption Spectrometry after Liquid Phase Microextraction with Pyrimidine-2-thiol Saeid Nazari1,2 1 Department of Chemistry, Faculty of Science, Sabzevar Tarbiat Moallem University, Sabzevar, Iran 2Department of Chemistry, Quchan Branch, Islamic Azad University, Quchan, Iran E-mail : nazari@, nazari@sttu.ac.ir Received December 18, 2010; revised February 3, 2011; accepted February 11, 2011 Abstract The liquid phase microextraction (LPME) was combined with the modified Graphite furnace atomic absorp- tion spectrometry (GF-AAS) for determination of lead in the water and solid samples. In a preconcentration step, lead was extracted from a 2 ml of its aqueous sample in the pH = 5 as lead-Pyrimidine-2-thiol cationic complex into a 4 µl drop of 1,2 dichloroethane and ammonium tetraphenylborate as counter ion immersed in the solution. In the drop, the lead-Pyrimidine-2-thiol ammonium tetraphenylborate ion associated complex was formed. After extraction, the microdrop was retracted and directly transferred into a graphite tube modi- fied by [W.Pd.Mg] (c). Some effective parameters on extraction and complex formation, such as type and volume of organic solvent, pH, concentration of chelating agent and counter ion, extraction time, stirring rate and effect of salt were optimized. Under the optimum conditions, the enrichment factor and recovery were 525% and 94%, respectively. The calibration graph was linear in the range of 0.01 - 12 µg·L–1 with correla- tion coefficient of 0.9975 under t