dielectric properties and the phase transition of pure and cerium doped calcium-barium-niobate介电性能和纯粹的相变和铈掺杂calcium-barium-niobate.pdfVIP

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dielectric properties and the phase transition of pure and cerium doped calcium-barium-niobate介电性能和纯粹的相变和铈掺杂calcium-barium-niobate.pdf

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dielectric properties and the phase transition of pure and cerium doped calcium-barium-niobate介电性能和纯粹的相变和铈掺杂calcium-barium-niobate

World Journal of Condensed Matter Physics, 2012, 2, 80-84 /10.4236/wjcmp.2012.22014 Published Online May 2012 (http://www.SciRP.org/journal/wjcmp) Dielectric Properties and the Phase Transition of Pure and Cerium Doped Calcium-Barium-Niobate 1 1 1 2 2 Alexander Niemer , Rainer Pankrath , Klaus Betzler , Manfred Burianek , Manfred Muehlberg 1Department of Physics, University of Osnabrück, Osnabrück, Germany; 2Institute of Crystallography, University of Cologne, Co- logne, Germany. Email: Klaus.Betzler@uos.de Received December 2nd, 2011; revised February 25th, 2012; accepted March 2nd, 2012 ABSTRACT The complex dielectric constant of pure and cerium doped calcium-barium-niobate (CBN) was studied at frequencies 20 Hz ≤f ≤ 1 MHz in the temperature range 300 K ≤ T ≤ 650 K and compared with the results for the well known ferro- electric relaxor strontium-barium-niobate (SBN). By the analysis of the systematically taken temperature and frequency dependent measurements of the dielectric constant the phase transition characteristic of the investigated materials was evaluated. From the results it must be assumed that CBN shows a slightly diffuse phase transition without relaxor be- havior. Doping with cerium yields a definitely different phase transition characteristic with some indications for a re- laxor type ferroelectric material, which are common from SBN. Keywords: 77.80.-e Ferroelectricity and Antiferroelectricity; 77.80.Jk Relaxor Ferroelectrics; 77.84.Ek Niobates and Tantalates; 77.22.Ch Permittivity (Dielectric Function) 1. Introduction studied. The measurements of the dielectric constant and a comparison to the results of SBN are used to study the The ferroelectric mat