direct cadmium monitoring in cigarette filters leachate by molecular fluorescence直接监测香烟过滤器镉渗滤液分子荧光.pdfVIP

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direct cadmium monitoring in cigarette filters leachate by molecular fluorescence直接监测香烟过滤器镉渗滤液分子荧光.pdf

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direct cadmium monitoring in cigarette filters leachate by molecular fluorescence直接监测香烟过滤器镉渗滤液分子荧光

Journal of Environmental Protection, 2012, 3, 187-193 187 /10.4236/jep.2012.32023 Published Online February 2012 (http://www.SciRP.org/journal/jep) Direct Cadmium Monitoring in Cigarette Filters Leachate by Molecular Fluorescence 1 2 2 1,2* María Carolina Talio , Tristán A. Bonfiglioli , Marta O. Luconi , Liliana P. Fernández 1Instituto de Química de San Luis (INQUISAL-CONICET), Chacabuco y Pedernera, San Luis, Argentina; 2Área de Química Analítica, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, San Luis, Argentina. * Email: lfernand@.ar Received November 17th, 2011; revised December 15th, 2011; accepted January 17th, 2012 ABSTRACT This work proposes a new direct flourimetric methodology for cadmium traces quantification based on its association with azo-reagent SPADNS and rhodamine B dye. Experimental variables that influence on fluorimetric sensibility were optimized using uni-variation assays. The calibration graph using zeroth order calibration was linear from 0.192 to 1.26 4 µg·L−1, with a correlation coefficient of 0.99. Under the optimal conditions, it was obtained a limit of detection of 10 0.057 µg·L−1 and a limit of quantification of 0.192 µg·L−1. The method showed good sensitivity, adequate selectivity with good tolerance to foreign ions, and was applied to the determination of trace amounts of cadmium in filters leachates coming from unsmoked, automatically smoked and smokers smoked cigarettes with satisfactory results. The proposed method represents an innovative application of luminescence to metal analysis comparable in sensitivity and accuracy to atomic spectroscopies. Keywords: Cadmium Traces; SPADNS; Rhodamine B;