dispersive liquid-liquid microextraction based on solidification of floating organic drop followed by gas chromatography-electron capture detector for determination of some pesticides in water samples英文论文.pdfVIP

SAGE-Hindawi Access to Research Chromatography Research International Volume 2011, Article ID 451712, 8 pages doi:10.4061/2011/451712 Research Article Dispersive Liquid-Liquid Microextraction Based on Solidification of Floating Organic Drop Followed by Gas Chromatography-Electron Capture Detector for Determination of Some Pesticides in Water Samples Mostafa Bashiri Juybari,1 Ali Mehdinia,2 Ali Jabbari,1 and Yadollah Yamini3 1 Department of Chemistry, Faculty of Sciences, K.N. Toosi University of Technology, Tehran 1969764499, Iran 2 Department of Marine Living Resources, Iranian National Institute for Oceanography, Tehran 1411813389, Iran 3 Department of Chemistry, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran Correspondence should be addressed to Ali Mehdinia, mehdi 3848@ Received 21 June 2011; Revised 24 August 2011; Accepted 5 September 2011 Academic Editor: Kanji Miyabe Copyright © 2011 Mostafa Bashiri Juybari et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. In this study dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO) followed by gas chromatography-electron capture detection (GC-ECD) was developed for determination of some pesticides in the water samples. Some important parameters, such as type and volumes of extraction and disperser solvent and salt effect on the extraction recovery of analytes from aqueous solution were investigated. Under the optimum conditions (extraction solvent: 1-undecanol, 15.0µL; disperser solvent: acetone, 1.0 mL, and without salt addition), the preconcentration factors were obtained ranged from 802 to 9