donnan electric potential dependence of intraparticle diffusion of malachite green in single cation exchange resin particles a laser trapping-microspectroscopy study唐南电位依赖性intraparticle扩散孔雀石绿的单一阳离子交换树脂粒子激光trapping-microspectroscopy研究.pdfVIP

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donnan electric potential dependence of intraparticle diffusion of malachite green in single cation exchange resin particles a laser trapping-microspectroscopy study唐南电位依赖性intraparticle扩散孔雀石绿的单一阳离子交换树脂粒子激光trapping-microspectroscopy研究.pdf

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donnan electric potential dependence of intraparticle diffusion of malachite green in single cation exchange resin particles a laser trapping-microspectroscopy study唐南电位依赖性intraparticle扩散孔雀石绿的单一阳离子交换树脂粒子激光trapping-microspectroscopy研究

American Journal of Analytical Chemistry , 2012, 3, 188-194 /10.4236/ajac.2012.33027 Published Online March 2012 (http://www.SciRP.org/journal/ajac) Donnan Electric Potential Dependence of Intraparticle Diffusion of Malachite Green in Single Cation Exchange Resin Particles: A Laser Trapping-Microspectroscopy Study Nguyen M. Cuong1,2, Shoji Ishizaka1,3, Noboru Kitamura1,4* 1Department of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Japan 2Institute of Marine Environment and Resources, Haiphong City, Vietnam 3Department of Chemistry, Graduate School of Science, Hiroshima University, Higashihiroshima-City, Japan 4Department of Chemical Sciences and Engineering, Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Japan * Email: kitamura@sci.hokudai.ac.jp Received December 28, 2011; revised February 3, 2012; accepted February 14, 2012 ABSTRACT A laser trapping-microspectroscopy technique combined with excitation energy transfer from a fluorescent cationic dye + + (Rhodamine B, RB ) to a non-fluorescent cationic dye (Malachite Green, MG ) was employed to study pH effects on the diffusion coefficients of MG+ + (D(MG )) in single cation-exchange resin microparticles with the diameters of 16 μm. + +