原创力文档effect of pedotpss layer and ito ozonization in arylenevinylene-co-pyrrolenevinylene (avpv) based solar cell devicespedotpss层和ito臭氧化在arylenevinylene-co-pyrrolenevinylene(avpv)为基础的太阳能电池设备.pdfVIP
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effect of pedotpss layer and ito ozonization in arylenevinylene-co-pyrrolenevinylene (avpv) based solar cell devicespedotpss层和ito臭氧化在arylenevinylene-co-pyrrolenevinylene(avpv)为基础的太阳能电池设备
Materials Sciences and Applications, 2011, 2, 1702-1707
doi:10.4236/msa.2011.212227 Published Online December 2011 (http://www.SciRP.org/journal/msa)
Effect of PEDOT:PSS Layer and ITO Ozonization
in Arylenevinylene-co-Pyrrolenevinylene (AVPV)
Based Solar Cell Devices
Ankur Solanki1,2, S. Sundar Kumar Iyer2,3, Ashish Garg1,2
1Department of Materials Science Engineering, Indian Institute of Technology, Kanpur, India; 2Samtel Center for Display Tech-
nologies, Indian Institute of Technology, Kanpur, India; 3Departmental of Electrical Engineering, Indian Institute of Technology,
Kanpur, India.
E-mail: solanki@iitk.ac.in
th st th
Received September 26 , 2011; revised November 1 , 2011; accepted November 17 , 2011.
ABSTRACT
Arylenevinylene-co-pyrrolenevinylene (AVPV) is polymer oligomer system derived from arylbridged bispyrroles which
has been explored for photovoltaic devices. In this paper, we show the dependence of the photovoltaic device parame-
ters on the anode surface treatment in an organic single layer photovoltaic device based on AVPV as an electron donor.
Since the total quantum efficiency includes the charge collection efficiency at the electrodes, experiments were carried
out to vary the anode (ITO) characteristics, achieved by using ITO with or without ozonization and with or without
PEDOT :PSS (Polyethylene dioxythiophene :Polystyrene sulphonic acid) layer. Devices fabricated on ITO anode (with-
out ozonization and without PEDOT:PSS) exhibited the maximum current density (Jsc = 1.3 µA·cm–2) as compared to
those devices where ITO was ozonized as well as had a PEDOT:PSS layer (Jsc = 0.1 µA·cm–2) measured under 1 sun
illumination of AM 1.5 through a calibrated solar simulator.
Keywords : AVPV, Organic Polymers, Ozonization, PEDOT :PSS, Organic Solar Cells
1. Introduction
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