selective detection of dopamine in the presence of ascorbic acid at poly (m-aminobenzene sulfonic acid)多巴胺的选择性检测的抗坏血酸在保利(m-aminobenzene磺酸).pdfVIP

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selective detection of dopamine in the presence of ascorbic acid at poly (m-aminobenzene sulfonic acid)多巴胺的选择性检测的抗坏血酸在保利(m-aminobenzene磺酸).pdf

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selective detection of dopamine in the presence of ascorbic acid at poly (m-aminobenzene sulfonic acid)多巴胺的选择性检测的抗坏血酸在保利(m-aminobenzene磺酸)

American Journal of Analytical Chemistry , 2011, 2, 582-588 doi:10.4236/ajac.2011.25066 Published Online September 2011 (http://www.SciRP.org/journal/ajac) Selective Detection of Dopamine in the Presence of Ascorbic Acid at Poly (m-Aminobenzene Sulfonic Acid) Gamze Erdoğdu1,*, Mehmet Mutluhan Mutlu2 1 Department of Chemistry, Faculty of Arts and Sciences, İnönü University, Malatya, Turkey 2Department of Chemistry, Faculty of Arts and Sciences, Harran University, Şanlıurfa, Turkey E-mail : gerdogdu@.tr Received August 4, 2010; revised October 26, 2010; accepted May 1, 2011 Abstract Poly (m-aminobenzene sulfonic acid, m-ABSA) films were electrochemically prepared by cyclic voltam- metry (CV) in 0.1 mol L–1 KCl solution. The dopamine (DA) selectivity of polymeric electrodes prepared at the different thicknesses was examined in the presence of ascorbic acid (AA). The results showed that the modified electrode showed an excellent electrocatalytical effect towards oxidation of dopamine (DA) and ascorbic acid (AA). Electrostatic interaction between the negatively charged poly(m-ABSA) film and either cationic DA species or anionic AA species favorably contributed to the redox response of DA and AA. Moreover, the regular and repetitive responses for dopamine were obtained even in the presence of the some interfering substances such as ascorbic acid, NaCl, NaClO , Na SO ,NaNO and KCl. 4 2 4 3 Keywords: Poly (m-Aminobenzene Sulfonic Acid), Dopamine, Ascorbic Acid 1. Introduction It is a possible way to overcome this problem