准东煤热解燃烧和气化过程中Na的行为及-中国电机工程学报.PDF

第 36 卷 第 16 期 中 国 电 机 工 程 学 报 Vol.36 No.16 Aug. 20, 2016 4396 2016 年 8 月 20 日 Proceedings of the CSEE ©2016 Chin.Soc.for Elec.Eng. DOI ：10.13334/j.0258-8013.pcsee.160379 文章编号：0258-8013 (2016) 16-4396-06 中图分类号：TK 16 准东煤热解、燃烧和气化过程中 Na 的行为及 高岭土的捕获作用 陈媛，许杨，盛昌栋 ( 东南大学能源与环境学院，江苏省 南京市 210096) Behavior of Na and Its Capture by Adding Kaolin During Devolatilization, Combustion and Gasification of Zhundong Coal CHEN Yuan, XU Yang, SHENG Changdong (School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu Province, China) ABSTRACT: Aiming at controlling particulate matter 关键词：细颗粒物；准东煤；Na ；高岭土；反应气氛 formation and Na behavior during the conversion of Zhundong coal, experiments were conducted in a drop-tube furnace to 0 引言 investigate the formation characteristics of particulate matter 准东煤因碱金属和碱土金属(alkali and alkaline and the contribution of Na during pulverized Zhundong coal earth metals，AAEMs)含量高，在燃烧发电利用过 reacting in devolatilization, combustion and gasification conditions. The impacts on the particulate matter formation and 程中易导致锅炉受热面的严重沾污及结渣等问题， the capture of Na by adding kaolin in the three environments 影响锅炉机组的安全、经济运行，因此，近年来得 were also studied. The results show that a certain amount of Na 到了广泛的关注和研究[1-4] 。细灰颗粒的沉积是受热 vaporizes during devolatilization, but char combustion and 面沾污初始沉积形成的主要原因。细灰颗粒尤其是 subsequent ashing are still the most important stages for Na evaporation. Gasification enhances Na evaporating as NaCl. 亚微米颗粒主要