以铈锆固溶体Ce-Zr-O为载体选择性催化氧化NO.docVIP

以铈锆固溶体Ce-Zr-O为载体选择性催化氧化NO 摘要：以铈锆固溶体(CexZr1-xO2)为载体，采用溶胶-凝胶法制备了不同铈锆比(Ce/Zr)及不同Cr负载量的催化剂，考察了该系列催化剂的NO催化氧化性能。结果表明，当Ce/Zr=0.25（质量比），Cr负载量为7%时的催化效果最佳，当反应温度T=300 deg;C，空速GHSV=20000 mL/(hbull;g)时，eta;NO=62.18%。X射线衍射、电子顺磁共振、X射线光电子能谱等表征结果表明，当Ce/Zr=0.25时，催化剂表面所产生的氧空位最多。12073 关键词：NO，催化氧化，铈锆固溶体，铬Cr TitleProperties of the Cr/CexZr1-xO2 for NO catalytic oxidation Abstract： NO oxidation reaction was studied over a series of Cr/CexZr1-xO2 catalysts with different Ce/Zr prepared by impregnation method to evaluate the correlation of their structural with catalytic performance. The results showed that Cr/Ce