壁纸水性油墨的研制+文献综述.doc

壁纸水性油墨的研制+文献综述 摘要:本论文用OP-21、SDS和MS-1复配乳化剂通过半连续核-壳乳液聚合分别制备了水性叔丙树脂、水性酮肼交联树脂和水性N-羟甲基丙烯酰胺交联丙烯酸树脂，测定了水性树脂的固含量、吸水率、粘度、耐水性、光泽度、干燥速度等性能以及对树脂膜进行红外表征。再以树脂乳液及适当的助剂制备了水性上光油并进行了粘度、光泽度、干燥速度、吸水率等性能的测定。研究表明，以N-羟甲基丙烯酰胺交联丙烯酸树脂为成膜物质所配置的水性上光油具有优异的光泽度、良好的耐水性、耐醇性、耐酸性和耐碱性。5976 关键词：水性树脂；性能；干燥速度；光泽度；粘度；水性上光油 Wallpaper with the development of water-based ink Abstract:This paper use the OP - 21, SDS and MS - 1 emulsifier to produce the water-borne tertiary carbonic acid vinyl ester crosslinking acrylate resin, water-borne ketone hydrazine crosslinking acrylate resin, and N-methylol acrylamide aqueous crosslinking acrylate resin by semi-continuous core - shell emulsion polymerization respectively，to complete the determination of various water-based resin solidss content, water absorption rate, viscosity, water resistance，glossperformance，drying time and other properties as well as on all kinds of resins for infrared characterization of lipid membranes.Finally,take emulsion as forming material,adding appropriate additives to produce the waterborne glazing oil,then measure the properties of viscosity, gloss performance,drying time, frictional resistance,water resistance,etc.The research shows that N-methylol acrylamide aqueous crosslinking acrylate resin as film forming material of waterborne glazing oil has excellent gloss performance, strong resistance to water, alcohol, acid, alkali, frictional resistance. Keywords: water-borne resin;performance;drying time;gloss;viscosity;water-borne glazing oil 目录 1 绪论1 2.5.6 粘度的测定18 2.5.7 光泽度的测定18 3 实验结果与讨论19 3.1 高性能水性树脂体系的选择19 3.2 水性叔丙体系树脂的表征与性能21 3.2.1 水性叔丙树脂结构的红外表征21 3.2.2 水性叔丙树脂的各项性能指标21 3.3 水性酮肼交联丙烯酸酯树脂的表征与性能22 3.3.1 水性酮肼交联丙烯酸酯树脂结构的红外表征22 3.3.2 水性酮肼交联丙烯酸酯树脂树脂的各项性能指标23 3.4 水性N-羟甲基交联丙烯酸酯树脂的表征与性能23 3.4.1 水性N-羟甲基交联丙烯酸酯树脂结构的红外表征23 3.4.2 水性N-羟甲基交联丙烯酸酯树脂的各项性能指标24 3.5 水性流变助剂对各体系上光油粘度的影响24 3.5.1 水性流变助剂对叔丙2号体系粘度的影响24 3.5.2 水性流变助剂对酮肼交联体系粘度的影响25 3.5.3 水性流变助剂对N-羟甲基丙烯酰胺交联体系粘度的影响26 3.5.4 水性流变助剂对3种不同体系的有效性研究26 3.6 不同体系的上光油粘度对其光泽度的影响28 3.6.1 叔丙2号体系上光油粘度对其光泽度的