晶化条件对水热合成的Cu-MCM41介孔分子筛物性参数的影响.docVIP

晶化条件对水热合成的Cu-MCM41介孔分子筛物性参数的影响 摘要：本采用水热合成法以正硅酸四乙酯(TEOS)和硝酸铜为原料，十六烷基三甲基溴化铵（CTAB）为模板剂，合成含铜介孔分子筛（Cu-MCM41）。并用X射线粉末衍射（XRD）仪和红外光谱（FT-IR）仪等对样品的结构进行表征，考察不同晶化条件（晶化压力和晶化时间）对样品孔径结构和有序性等物性参数的影响。研究结果表明：随着晶化压力的增大，Cu-MCM41介孔分子筛晶化程度增大，介孔有序性增强；随着晶化时间的增加介孔有序性增强。11599 关键词：水热合成；晶化条件；Cu-MCM-41介孔分子筛；物性参数 The Effect of Crystallization Conditions to Cu-MCM41 Physical Parameters Under the Condition of Hydrothermal Synthesis Abstract：In this paper, Samples of Cu-MCM41 were synthesized by the hydrothermal method and using tetraethyl orthosilicate (TEOS) and copper nitrate as raw materials, cetyl trimethyl ammonium