由1-卤代酮合成硒醚.docVIP

由1-卤代酮合成硒醚 摘要:有机硒化合物是有机合成中非常重要的中间体和合成试剂，而二硒醚在有机硒试剂中是应用最广泛的，在有机硒化学中占有极其重要的地位。本研究了在常压下，以DMF 作为溶剂，用氢氧化钠作为辅助剂，以1-卤代酮为原料，用Se/CO/H2O体系来还原硒化，合成相应的对称二硒醚。实现了在常压的条件下用Se/CO/H2O 体系还原1-卤代酮到二硒醚。12265 关键词:常压；1-卤代酮；对称二硒醚；还原硒化；合成 The Synthesis of Symmetrical Diselenide with 1-Haloketone Abstract: Organic selenium compounds are very important synthetic agent and intermediate in organic synthesis,and diselenide is the most widely used in organic selenium reagent, and plays an important role in organoselenium chemical. It is studied that the synthesis of symmetrical diselenide with 1-haloketone,and DMF as so