稀土离子掺杂TiO2纳米管阵列的制备.docVIP

稀土离子掺杂TiO2纳米管阵列的制备 摘要：本论文采用阳极氧化法制备稀土离子La、Eu掺杂TiO2纳米管阵列，通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)、紫外-可见漫反射(UV-vis)、荧光分光光度计(FS)、傅立叶变换红外光谱仪(FT-IR)等测试方法对催化剂进行表征，分析了稀土离子La、Eu掺杂TiO2纳米管的晶型结构、表面形貌和光学性能。结果表明：La、Eu掺杂对TiO2纳米管阵列晶型无明显影响；La、Eu掺杂后TiO2纳米管阵列表面形貌变化较大，表面形貌随浓度的不同而不同，部分呈现一层一层的片状纳米管；La、Eu的最优掺杂量分别为1.0wt%、1.2wt%，在500 W的汞灯下照射2h，对甲基橙的降解率分别为83.6％和70.9％，说明稀土La、Eu掺杂提高了TiO2纳米管阵列的光催化活性。9052 关键词：TiO2纳米管阵列; 阳极氧化法; 稀土离子掺杂; 光催化; 甲基橙 Preparation of Rare-earth Ion-doped TiO2 Nanotube Arrays Abstract: In this paper,La, Eu doped TiO2 nanotube arrays were prepared by anodic oxidation. The catalysts were charactered by X-ray diffraction(XRD), scanning electron microscopy(SEM), UV-visible diffuse reflectance(UV-Vis), fluorescence spectroscopy(FS), fourier transform infrared spectroscopy (FT-IR) and other testing methods. The crystal structure, surface morphology and optical performance of La, Eu doped TiO2 nanotube arrays were analyzed. The results demonstrated that La, Eu doping had no effect on crystalline. The surface morphology varied with the concentration and flaky nanotubes partially came out in layers. The optimum doping amount of La and Eu separately were 1.0% and 1.2%. Their degradation rates of methyl orange were 83.6% and 70.9% respectively under 500W mercury lamped after 2h. All these described that the photocatalytic activity of La, Eu doped TiO2 nanotube arrays were effectively improved. Key Words: TiO2 nanotube array; Anodic oxidation; Rare-earth doped; Photocatalytic; Methyl orange 目录 由于稀土元素具有不完全充满的4f轨道和空的5d轨道，易产生多电子组态，可以成为光生电子或空穴的浅势捕获陷阱，延长TiO2光生电子与空穴对的复合时间，提高其光催化活性；同时由于稀土元素可以吸收紫外光区、可见光区、红外光区的各种波长的电磁波辐射，可更有效地利用太阳能[18-20]。因此，稀土离子掺杂在TiO2改性和光催化剂方面应用广泛。本文采用阳极氧化法制得La/TiO2和Eu/TiO2光催化剂，采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)分析了样品的晶型结构和表面形貌，通过甲基橙降解实验分析了稀土离子La、Eu掺杂TiO2纳米管的光催化性能。 1 实验部分 1.1 试剂与仪器 无水乙醇[CH3CH2OH](分析纯，天津市凯通化学试剂有限公司)；氟化钠[NaF](分析纯，上海经济区江城试剂厂)；浓硫酸[H2SO4](分析纯，洛阳市化学试剂厂)；浓硝酸[HNO3](分析纯，开封市方晶化学试剂有限公司)。 数显智能控温磁力搅拌器(SZCL-2，巩义市予华仪器有限公司)；电子天平(AL204，梅特勒-托利多仪器有限公司)；马弗炉(型号为XY-1400，南阳市鑫宇电热元器件制品有限公司)；CA17