丙烯醇为起始剂,与不同比例的POEO丙烯醇醚.docVIP

摘 要 聚合物型原油破乳剂具有破乳能力强、脱水速度快、用药量少、破乳温度比较低的特点，对各类原油乳状液有较广泛的适应性。论文以丙烯醇为起始剂，与不同比例的环氧丙烷(PO)、环氧乙烷(EO)反应合成丙烯醇醚，通过脱水性能找到丙烯醇与PO、PO与EO的最佳比例，再将该丙烯醇醚分别与丙烯酰胺(AM)、丙烯酸(AA)、氯丙烯反应聚合得到烯丙基类的线型聚合物，并对其结构进行了红外表征，通过相关性能测试，优化了聚合反应条件，实验结果表明： （1）丙烯醇与PO的比例为1:7，PO与EO的最佳比例为7:3。 （2）在AM与醇醚的聚合反应中，反应条件对反应的重要性依次为：单体浓度单体配比反应温度引发剂用量，最佳实验条件为：单体为，反应温度为℃，引发剂用量为%。单体配比反应温度引发剂用量单体配比为1:1，反应温度为75℃引发剂用量为1%单体配比反应温度引发剂用量单体配比为1:1，反应温度为℃，引发剂用量为%。 对合成得到的聚合物进行降解实验，实验结果表明丙烯酰胺类聚合物具有明显的降解性能，而丙烯酸类聚合物和氯丙烯类聚合物降解性则比较弱。 关键词： 破乳剂 丙烯醇 丙烯酰胺 丙烯酸 降解性能 Abstract Polymeric crude oil demulsifier has strong demulsification ability, faster dehydration speed, low drug use, and the demulsification temperature is relatively low. There are wider adaptability various types of crude oil emulsion. The thesis is based on allyl alcohol as the initiator synthesis propylene glycol ethers with different rations of propylene oxide, ethylene oxide, by using the dewatering performance to find the best ratio between allyl alcohol and PO, PO and EO. The synthesized propylene glycol ethers react with acrylamide, acrylic acid and propylene chlorine to obtained linear polymer allyl. Infrared spectroscopy were used to characterize the polymer, and optimize the polymerization reaction conditions. (1)Experimental results demonstrates that the best ratio between allyl alcohol and PO is 1:7, PO and EO is 7:3. (2)In polymerization of AM and propylene glycol ethers, reaction condition on the experiment of importance is followed by monomer concentration, monomer ratio, temperature, initiator dosage. The best experimental conditions as follows: 40% monomer concentration, monomer ratio of 2:1, temperature of 50℃, initiator dosage of 0.25%. (3)In the polymerization of acrylic and propylene glylene glycol ethers trials, reaction condition on the experiment of importance is followed by monomer ratio, temperature, initiator dosage. The best experimental conditions as follows: monomer ratio of 1:1, temperature of 75℃, initiator dosage of 1