spectroscopic studies of ln(iii) complexes with polyoxometalates in solids, and aqueous and non-aqueous solutions光谱的研究ln(iii)与杂多酸复合物固体和水和无水的解决方案.pdfVIP

Vol. 05 INTERNATIONAL JOURNAL OF PHOTOENERGY 2003 Spectroscopic studies of Ln(III) complexes with polyoxometalates in solids, and aqueous and non-aqueous solutions Stefan Lis,1,† Slawomir But,1 Andrzej M. Kłonkowski,2 and Beata Grobelna2 1 Faculty of Chemistry, Adam Mickiewicz University, 60–780 Pozna´n, Poland 2 Department of Chemistry, University of Gda´nsk, 80–952 Gda´nsk, Poland Abstract. Chosen polyoxometalate (POM) anions and their lanthanide(III) complexes, LnPOM, have been synthesized and spectroscopically characterized in solid state, aqueous and non-aqueous solutions. POMs, such as Keggin’s, Dawson’s and Anderson’s type, Na9EuW10O36, compositions that function as in- organic cryptands ( [(Na )P5W30O110 ]14−-Preyssler anion, and [ (Na )As4W40 O140 ]27−), containing inorganic (Na+, K+, NH+) or organic (tetrabutylammonium, NBu+) counter cations were obtained and their Ln (III ) com- 4 4 plexes (sandwiched and encapsulated) studied. The synthesized compounds were identified using elemental and thermogravimetric analysis, UV-Vis spectrophotometry and FTIR spectroscopy. The complexation stud- ies were carried out with the use Nd (III ) and Er (III ) optical absorption and Eu (III ) luminescence spectroscopy. Luminescence characterization, including results of intensity, quantum yields and luminescence lifetimes of EuPOM complexes in aqueous, non-aqueous solutions (DMF, DMSO, acetonitryle) and solid are discussed. Based on luminescence lifetime measurements of the Eu (III ) ion the hydration numbers of its sandwiched (efficient e