synthesis and characterization of boron trifluoride doped high performance polyaniline高性能三氟化硼掺杂聚苯胺的合成和表征.pdfVIP

ISSN: 0973-4945; CODEN ECJHAO E-Journal of Chemistry 2012, 9(4), 2332-2337 Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline 1* 2 1 K. BASAVAIAH , D. SAMSONU , AND A. V. PRASADA RAO 1Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam- 530003, India 2Departments of Organic, Foods, Drugs and Water, Andhra University, Visakhapatnam- 530003, India klbasu@ Received 28 July 2011; Accepted 4 October 201 1 Abstract: We report simple synthesis of boron trifluoride (BF ) doped defect 3 free high performance polyaniline (HPPANI) in two step method. Firstly, HPPANI was prepared via self-stabilization dispersion polymerization method in a heterogeneous reaction medium. Second step involves doping of emeraldine base form of HPPANI with boron trifluoride under reduced vacuum. The resultants BF3 doped HPPANI have been well characterized by using UV- Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetry. The spectroscopic data indicated that the interaction between HPPANI and BF .Thermogravimetry