spiropyrans containing the reactive substituents in the 2h-chromene moietyspiropyrans包含活性的取代基的2 h-chromene一半.pdfVIP

Hindawi Publishing Corporation International Journal of Photoenergy Volume 2007, Article ID 10583, 6 pages doi:10.1155/2007/10583 Research Article Spiropyrans Containing the Reactive Substituents in the 2H-Chromene Moiety B. S. Lukyanov,1 Yu. S. Alekseenko,2 E. L. Mukhanov,1 M. B. Lukyanova,1 A. V. Metelitsa,1 K. N. Khalanskij,1 V. V. Tkachev,3 and O. N. Ryashin1 1 Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don 344090, Russia 2 South Scientific Center of Russian Academy of Science, Rostov-on-Don 344006, Russia 3 Institute of Problems of Chemical Physics, Russian Academy of Scienc, Chernogolovka, Moscow Region 142432, Russia Received 26 February 2006; Revised 15 November 2006; Accepted 2 January 2007 Recommended by Sabry Abdel-Mottaleb Some spiropyrans containing functional substituents in the [2H ]-chromene part of the molecule were synthesized and their pho- tochromic properties in solution and solid state were investigated. The presence of the formyl group in the [2H ]-chromene frag- ment enhances the possibility to show photochromic properties in solution. Copyright © 2007 B. S. Lukyanov et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 1. INTRODUCTION atives with specific photochromic properties for potential practical application. Photochromism is a reversible conversion between differ- ently-colored isomers induced in one or both directions by 2. METHODS AND MATERIALS absorption of electromagnetic radiation [1]. Many classes of organic compounds can r