synthesis and characterization of well-defined soluble - and -functionalized polymers via raft copolymerization合成和表征定义良好的可溶性和功能化的聚合物通过筏共聚.pdfVIP

Hindawi Publishing Corporation International Journal of Polymer Science Volume 2010, Article ID 340926, 7 pages doi:10.1155/2010/340926 Research Article Synthesis and Characterization of Well-Defined Soluble Alq3- and Znq2-Functionalized Polymers via RAFT Copolymerization Chengchao Wang, Wei Zhang, Nianchen Zhou, Yansheng Qiu, Zhengping Cheng, and Xiulin Zhu Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China Correspondence should be addressed to Xiulin Zhu, xlzhu@ Received 31 October 2009; Accepted 21 February 2010 Academic Editor: Jinying Yuan Copyright © 2010 Chengchao Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The reversible addition-fragmentation chain transfer (RAFT) copolymerizations of 2-((8-hydroxyquinolin-5-yl)methoxy)ethyl methacrylate (HQHEMA) with styrene (St) or methyl methacrylate (MMA) were successfully carried out in the presence of 2-cyanoprop-2-yl dithionaphthalenoate (CPDN). The polymerization behaviors showed the typical living natures by the first- order polymerization kinetics, the linear dependence of molecular weights of the polymers on the monomer conversions with the relatively narrow molecular weight distributions (M /M ), and the successful chain extension experiments. The soluble polymers w n having tris(8-hydroxyquinoline)aluminum (Alq ) and bis(8-hydroxyquinoline) znic(II) (Znq ) side chains were obtained via