The Power of Thiolene Chemistry Hawker （Thiolene化学小贩的力量）.pdf

The Power of Thiol-ene Chemistry MATTHEW J. KADE,1,3 DANIEL J. BURKE,1,3 CRAIG J. HAWKER1,2,3 1Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106 2Department of Materials, University of California, Santa Barbara, California 93106 3Materials Research Laboratory, University of California, Santa Barbara, California 93106 Received 28 October 2009; accepted 6 November 2009 DOI: 10.1002/pola.23824 Published online in Wiley InterScience (). ABSTRACT: As a tribute to Professor Charlie Hoyle, we take the trate these features, the utility of thiol-ene reactions for net- opportunity to review the impact of thiol-ene chemistry on work formation, polymer functionalization, dendrimer synthesis, polymer and materials science over the past 5 years. During and the decoration of three-dimensional objects is discussed. this time, a renaissance in thiol-ene chemistry has occurred Also, the development of the closely related thiol-yne chemistry C with recent progress demonstrating its unique advantages is described. V 2010 Wiley Periodicals, Inc. J Polym Sci Part A: when compared with traditional coupling and functionalization Polym Chem 48: 743–750, 2010 strategies. Additionally, the robust nature of thiol-ene chemis- try allows for the preparation of well-defined materials with KEYWORDS: click chemistry; crosslinking; synthesis; thin films; few structural limitations and synthetic requirements. To illus- thiol-ene Matthew J. Kade received his BS in Chemistry and Economics from the University of Massachu- setts, Amherst in 2005, where he conducted rese