β-胡萝卜素液晶的制备及其稳定性研究-河南农业科学.PDFVIP

※基础研究 食品科学 2009, Vol. 30, No. 11 11 β-胡萝卜素液晶的制备及其稳定性研究 1,2 1, 1 颜秀花 ，王正武 * ，刘 峰 (1.上海交通大学农业与生物学院，上海 200240 ；2.盐城工学院化学与生物工程学院，江苏 盐城 224003) 摘 要：通过绘制拟三元相图对食品级 β- 胡萝卜素的液晶配方和工艺进行研究；用偏光显微镜、流变学方法等对 非离子表面活性剂 EL-35/ 丁酸乙酯/ 水的溶致液晶的形成、微观结构、动态流变性质及体系相态进行研究；对相 同浓度 β- 胡萝卜素的液晶、微乳液和丁酸乙酯溶液进行光和pH 值稳定性实验。结果表明：25 ℃下， β- 胡萝卜 素在 EL-35:丁酸乙酯:水 =1:1:1 体系的液晶、微乳液和油溶液中对光都比较敏感，但在液晶中相对稳定：pH 值对微 乳液和丁酸乙酯油溶液中的 β- 胡萝卜素稳定性有影响，对液晶中的几乎没有影响。 关键词： β- 胡萝卜素；溶致液晶；制备；稳定性 Preparation and Stability of β-Carotene Liquid Crystal YAN Xiu-hua 1,2 ，WANG Zheng-wu1,*，LIU Feng1 (1. School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China； 2. College of Chemical and Biological,Yancheng Institute of Technology,Yancheng 224003, China) Abstract：Pseudo ternary phase diagram was conducted using water titration method to choose emulsifier EL-35-ethyl butyrate- water system to prepare β-carotene liquid crystal, and the microstructures and rheological properties of 4 emulsifier EL-35-ethyl butyrate-water systems (A1, A2, A3 and A4) with different water masses (the mass ratio of emulsifier EL-35 to ethyl butyrate were fixed at 5:5) were characterized with polarizing microscopy and rheometer. Effects of external conditions, including pH value, preservative (sodium benzoate), saturated ethyl butyrate solution of β-carotene and water amount on stability of this system were discussed. Furthermore, effects of sunlight and pH on the stability of β-carotene were compared in different multiphase systems, including liquid crystal, microemulsion and ethyl butyrate solution. Results revealed that the