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非对称超级电容器负极材料研究进展 research progress in anodes of asymmetric supercapacitors
第4 卷 第4 期 新 能 源 进 展 Vol. 4 No. 4
2016 年8 月 ADVANCES IN NEW AND RENEWABLE ENERGY Aug. 2016
文章编号:2095-560X (2016 )04-0286-11
非对称超级电容器负极材料研究进展*
程昕予,于明浩,卢锡洪†
(中山大学化学与化学工程学院,生物无机与合成化学教育部重点实验室,广州 510275 )
摘 要:超级电容器作为一种新型储能器件受到了全球的广泛关注,其中非对称超级电容器比对称超级电容器具有
更大的能量密度。然而近年来,研究的重点主要集中于非对称超级电容器的正极材料,相比而言,其负极材料的发
展较为缓慢,影响了整个非对称超级电容器器件的性能发挥。本文介绍了近年来非对称超级电容器负极材料的研究
进展,主要分为碳材料电极、金属氧化物电极、金属氮化物电极以及金属硫化物电极。我们也对基于这些负极材料
组装的非对称超级电容器器件进行了介绍。最后,我们提出了非对称超级电容器未来的发展趋势以及所面临的挑战。
关键词:非对称;超级电容器;负极
中图分类号:TK02 文献标志码:A doi :10.3969/j.issn.2095-560X.2016.04.005
Research Progress in Anodes of Asymmetric Supercapacitors
CHENG Xin-yu, YU Ming-hao, LU Xi-hong
(MOE of the Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen
University, Guangzhou 510275, China)
Abstract: Supercapacitors, which serve as a kind of novel energy storage devices, have aroused great attention all over the
world. Among them, asymmetric supercapacitors present substantially higher energy densities than those of symmetric
ones. However, the imbalanced development of supercapacitor anodes can hardly match that of cathodes, which severely
limits the performance of the whole device. In this review, the recent research progress is briefly summarized on anodes of
asymmetric supercapacitors categorizing into carbon based, metal oxides based, metal nitrides based, and metal sulfides
based electrodes. Besides, the electrochemical performance of the ASC devices assembled with those anodes is discussed.
Finally, the future trend and challenges of asymmetric supercapaci
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