非化学计量(la0.6sr0.4)xco0.2fe0.8o3-δ阴极材料的制备与性能 fabrication and characterization of non-stoichiometry (la0 .6 sr0 .4)xco0 .2fe0 .8o3 - δ cathode for sofcs.pdfVIP
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非化学计量(la0.6sr0.4)xco0.2fe0.8o3-δ阴极材料的制备与性能 fabrication and characterization of non-stoichiometry (la0 .6 sr0 .4)xco0 .2fe0 .8o3 - δ cathode for sofcs
37 1 Vol.37 No.1
2016 02 Journalof Changchun University of Technology Feb.2016
DOI :10 .15923/ .cnki.cn22‐1382/t.2016 .1 .04
j
(La Sr ) Co Fe O
0 .6 0 .4 x 0 .2 0 .8 3- δ
, , , , *
(, 130012)
0 .6 0 .4 x 0 .2 0 .8 3 - δ
:(La Sr ) Co Fe O (x= 0 .95 ,0 .97 ,1 .00 ,1 .03 ,1 .05)
。 X (XRD)(SEM),
(EIS)。 ,750 ℃ 3 h
,A 。 700 ℃ ,x= 1 .05
2
0 .6 0 .4 x 0 .2 0 .8 3 - δ
0 .086 3 Ω ·cm ,x= 1 .00 50% ,(La Sr ) Co Fe O
。
: ;;SOFC;
:O 614 .33 :A :1674‐1374(2016)01‐0015‐05
Fabrication and charact erization of non‐stoichiomet ry
(La Sr ) Co Fe O cathode for SOFCs
0 .6 0 .4 x 0 .2 0 .8 3 - δ
ZHANG Guanming, SUN Haoran, WANG Yuan,
*
CHEN Lei, ZHOU Defeng
(School of Electrical Electronic Engineering ,Changchun University of Technology ,Changchun 130012 ,China)
0 .6 0 .4 x 0 .2 0 .8 3 - δ
Abstract : (La Sr ) Co Fe O (x= 0 .95 , 0 .97 , 1 .00 , 1 .03 , 1 .05) series cathode materials are
prepared with sol‐ el method.The structure and microstructure of sample are characterized by X‐rayg
diffraction (XRD) and scanning electron microscope (SEM),andtheelectricalconductivity aretested
by electrochemical impedance spectrum (EIS).Resultsindicate:orthorhombicperovskite structureis
formed after sintering 3 hoursat 750 ℃ ;A‐siteof non‐stoichiomet
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