AA SA在丙酮GA中的溶解度.pdf

Article pubs.acs.org/jced Solubilities of Adipic Acid and Succinic Acid in a Glutaric Acid + Acetone or n‑Butanol Mixture Yanyan Li,† Yatao Wang,‡ Zhuoyuan Ning,† Jianfang Cui, ‡ Qiaoye Wu,† and Xunqiu Wang*,† †School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, People’s Republic of China ‡Coal Chemical RD Center, Kailuan Group, Tangshan, Hebei 063611, People’s Republic of China ABSTRACT: In order to provide thermodynamic data for mixed dibasic acid separation technology, the solubilities of adipic acid (AA) and succinic acid (SA) in glutaric acid (GA) + acetone mixture and GA + n-butanol mixture were measured by dynamic method at atmospheric pressure. The mass fraction of GA (wGA) ranged from (0 to 30.11) %. The results show that solubilities of AA and SA in acetone or n-butanol increased with increasing mass fraction of GA in the mixed solvent GA and acetone (or n-butanol) at the same temperature. The ideal solution equation, Apelblat equation, and λh equation were applied to correlation of the experimental solubility data, which were all in good agreement with the three equations. The Apelblat equation is regarded as the best one of the three equations for describing the dissolving of two acids in solvent at the same time. 1. INTRODUCTION Large amounts of dibasic acid (DBA) were produced as a kind of byproduct during the nitric acid oxidation of cyclohexanol or cyclohexanone with copper- and vanadium-based catalysts.1 For instance, DBA output of adipic acid (AA) production units of China Pingmei Shenma Group alone was over 5000 tons per year. The components of D