苯丙乳液五元共聚合成条件的研究王华锋袁邓.pdf

8 卷 2 期 天 津 工 业 大 学 学 报 Vol.28 No.2 圆园园9 年4 月 韵哉砸晕粤蕴 韵云 栽陨粤晕 陨晕 孕韵蕴再栽耘悦匀晕陨悦 哉晕陨灾耘砸杂陨栽再 April 2009 苯丙乳液五元共聚合成条件的研究 华锋 邓宝祥 徐小波 渊天津工业大学 材料科学与化学工程学院袁天津 300 160冤 摘 要 甲基丙烯酸甲酯 MMA 冤尧苯乙烯 St冤尧丙烯酸丁酯 BA冤和丙烯腈 AN 冤为主单体袁丙烯酸 AA 冤为功能性单 体尧MS-1 和OP-10 为复合乳化剂袁采用预乳化工艺尧半连续种子乳液聚合合成性能优异的五元共聚苯丙乳 液袁探讨软硬单体尧功能性单体尧乳化剂和链转移剂对乳液性能的影响.结果表明袁当丙烯酸质量分数为3%尧乳 化剂质量分数为3%尧MS-1 和OP-10 质量比为2 颐 1尧链转移剂质量分数为2%时袁乳液综合性能良好. 关键词院预乳化工艺曰复合型乳化剂曰功能性单体曰链转移剂 中图分类号 TQ316.334 文献标识码 A 文章编号 员远苑员原园 源载渊 园园9 冤园2原园园59原园4 Study on five-component synthesis of styrene-acrylic emulsion WANG Hua-feng 袁 DENG Bao-xiang 袁 XU Xiao-bo 渊School of Material Science and Chemical Engineering 袁 Tianjin Polytechnic University 袁Tianjin 300 160 袁 China 冤 Abstract 院 A kind of styrene -acrylic emulsion with excellent performance was synthesized by polymerization of methyl methacrylate 袁styrene 袁butyl acrylate and acrylonitrile 渊as the main monomers 冤 and acrylic acid 渊as the functional monomer冤 when the mixed emulsifiers of MS-1 and the non-ionic emulsifier of OP-10 were used and pre -emulsification technology and semi -continuous seed emulsion polymerization were introduced援 The effects of the ratio between soft monomer and hard monomer 袁functional monomer 袁 emulsifier and chain - transfer agent on the properties of emulsions were discussed援 It is found that the latex with outstanding performance is obtained 袁 when the amount of acrylic acid is 3% 袁 the amount of emulsifiers was 3% 袁 MS-1 颐 OP-10 = 2 颐 1袁 the amount of chain-agent is 2%.