a possibility for construction of an iodine cleaning system based on doping for π-conjugated polymers可能建设π-conjugated碘清洗系统基于掺杂的聚合物.pdfVIP

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a possibility for construction of an iodine cleaning system based on doping for π-conjugated polymers可能建设π-conjugated碘清洗系统基于掺杂的聚合物.pdf

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a possibility for construction of an iodine cleaning system based on doping for π-conjugated polymers可能建设π-conjugated碘清洗系统基于掺杂的聚合物

Polymers 2011, 3, 875-885; doi:10.3390/polym3020875 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Communication A Possibility for Construction of an Iodine Cleaning System Based on Doping for -Conjugated Polymers Hiromasa Goto Institute of Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, 305-8573, Japan; E-Mail: gotoh@ims.tsukuba.ac.jp; Tel.: +81-29-853-5128; Fax: +81-29-853-4490 Received: 12 April 2011; in revisedform: 4 May 2011 / Accepted: 12 May 2011 / Published: 16 May 2011 Abstract: An iodine accumulation method using polyaniline (PANI) and a textile composite is proposed. PANI/pulp paper sheets prepared by a paper making technique are suitable for iodine adsorption, because of good processability. The PANI-based paper sheets can be applied for iodine cleanup as air filters, water filters, and floorcloth. This concept may lead to a development of an iodine cleaning machine or iodine shield cloth based on -conjugated polymer composites. In-situ vapor phase doping of iodine, observation of surface images, and IR measurements are carried out to examine iodine doping function for the PANI/pulp paper sheets. Keywords: iodine accumulator; intercalation; polyaniline; pulp; textile 1. Introduction Since the discovery of halogen doping effect for polyacetylene which confirmed dramatic increase of electrical conductivity, the development of conducting polymers for practical applications has been rapid. These new