a new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium and the crystal structure of its palladium (ii) complex一个新的异戊benzothiazolyl亚砜作为钯的萃取剂和钯(ii)的晶体结构复杂.pdfVIP

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a new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium and the crystal structure of its palladium (ii) complex一个新的异戊benzothiazolyl亚砜作为钯的萃取剂和钯(ii)的晶体结构复杂.pdf

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a new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium and the crystal structure of its palladium (ii) complex一个新的异戊benzothiazolyl亚砜作为钯的萃取剂和钯(ii)的晶体结构复杂

Molecules 2005, 10, 912-921 molecules ISSN 1420-3049 A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium and the Crystal Structure of its Palladium (II) Complex Yao-Wei Li 1, Guo-Bang Gu 1,*, Hai-Yang Liu 1, 2,*, Herman H. Y. Sung 2, Ian D. Williams 2 and Chi-K. Chang 2,* 1 Department of Applied Chemistry, South China University of Technology, Guangzhou 510640, P.R. China. Tel.: (+86)-20 Fax: (+86)-20 2 Department of Chemistry, The Hong Kong University of Science and Technology, Hong Kong, P.R. China. * Authors to whom correspondence should be addressed. E-mail: chgbgu@; chhyliu@; chang@ust.hk Received: 12 September 2004; in revised form: 6 February 2005 / Accepted: 15 February 2005 / Published: 31 August 2005 Abstract: A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO) Cl ] in the 2 2 extraction. X-ray crystal structure determination revealed PdCl2(ABSO)2 is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom. Keywords: Iso-amyl benzothiazolyl sulfoxide; Palladium; Solvent extraction; Crystal structure Introduction