塑料的内应力控制改性（Internal stress control of plastics）.docVIP

塑料的内应力控制改性（Internal stress control of plastics） Internal stress control of plastics Internal stress of plastics refers to an inherent stress produced by the process of melting of plastics due to the orientation of macromolecule chains and cooling and shrinkage. The essence of internal stress is not balanced conformation of molecular chain formed in the melting process, the imbalance in the conformation of curing not immediately cooling return to the equilibrium conformation and adapt to environmental conditions, the imbalance of high elastic deformation of the conformation is a kind of reversible, high elastic deformation and the usual to freeze energy stored in plastic products, under suitable conditions, the forced unstable conformation will transform to the conformational freedom of the stability of the potential energy into kinetic energy release. When the force between the macromolecular chains and the forces of entanglement can not withstand this kinetic energy, the internal stress balance is destroyed, and the plastic products will cause stress cracking and warpage. Almost all plastic products will have varying degrees of internal stress, especially plastic injection products are more obvious stress. The existence of internal stress not only causes warpage and cracking of plastic products during storage and use, but also affects the mechanical properties, optical properties, electrical properties and appearance quality of plastic products. For this reason, we must find out the internal stresses and to eliminate internal stress and reduce the stress inside the plastic products, and the residual stress in the plastic products are distributed as evenly as possible, to avoid the phenomenon of stress concentration, thereby improving the plastic mechanical thermal properties 1. Causes of internal stress in plastics There are many reasons for the internal stress, such as plastic melt by stronger shear in the machining process, orientation and crystallization process