acid-catalysed conversion of saccharides into furanic aldehydes in the presence of three-dimensional mesoporous al-tud-1acid-catalysed糖类转化为furanic醛的三维介孔al-tud-1.pdfVIP

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acid-catalysed conversion of saccharides into furanic aldehydes in the presence of three-dimensional mesoporous al-tud-1acid-catalysed糖类转化为furanic醛的三维介孔al-tud-1.pdf

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acid-catalysed conversion of saccharides into furanic aldehydes in the presence of three-dimensional mesoporous al-tud-1acid-catalysed糖类转化为furanic醛的三维介孔al-tud-1

Molecules 2010, 15, 3863-3877; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Acid-Catalysed Conversion of Saccharides into Furanic Aldehydes in the Presence of Three-Dimensional Mesoporous Al-TUD-1 Sérgio Lima 1, Margarida M. Antunes 1, Auguste Fernandes 2, Martyn Pillinger 1, Maria Filipa Ribeiro 2 and Anabela A. Valente 1,* 1 Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal; E-Mails: sergiolima@ua.pt (S.L.); margarida.antunes@ua.pt (M.M.A.); mpillinger@ua.pt (M.P.) 2 Institute for Biotechnology and Bioengineering, Centre for Biological and Chemical Engineering, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; E-Mails: auguste.fernandes@ist.utl.pt (A.F.); filipa.ribeiro@ist.utl.pt (M.F.R.) * Author to whom correspondence should be addressed; E-Mail: atav@ua.pt; Tel.: +351-234-370-603; Fax: +351-234-401-470. Received: 13 April 2010; in revised form: 24 May 2010 / Accepted: 26 May 2010 / Published: 28 May 2010 Abstract: The one-pot acid-catalysed conversion of mono/di/polysaccharides (inulin, xylan, cellobiose, sucrose, glucose, fructose, xylose) into 2-furfuraldehyde (FUR) or 5-hydroxymethylfurfural (HMF) in the presence of aluminium-containing mesoporous TUD-1 (denoted as Al-TUD-1, Si/Al = 21), at 170 ºC was investigated. Xylose gave 60% FUR yield after 6 h reaction; hexose-based mono/disaccharides gave less than 20% HMF yield; polysaccharides gave less than 20 wt % FUR or HMF