乙酸乙酯的合成（Synthesis of ethyl acetate）.docVIP

乙酸乙酯的合成（Synthesis of ethyl acetate） Synthesis of ethyl acetate Teaching requirements: Understand the principle and method of preparation of carboxylic acid esters from alcohols and carboxylic acid Master the method for the synthesis of ester (reversible reaction) control and reaction conditions Master the principle and method of separation and purification of products Study of organic liquid distillation, washing and drying and other basic operations Preview content: The dropping funnel and the use of the separatory funnel. Distillation operation Extraction and washing Understand the nature and method of using concentrated sulfuric acid Ethyl acetate, acetic acid, ethanol and water density, melting point and boiling point parameters Three, the basic operation EMBED PBrush Device for preparing ethyl acetate figure Four, the experimental principle: Ethyl acetate from acetic acid and ethanol in a small amount of concentrated sulfuric acid as catalyst prepared. The main reaction: EMBED Equation.3 Side effects: EMBED Equation.3 (140 to 150 DEG C) In response, in addition to sulfuric acid acts as a catalyst, but also absorbs the water of reaction, it is conducive to the formation of the ester. If the reaction temperature is too high, causing the occurrence of side reaction to Diethyl ether. In order to improve the yield in this experiment by increasing the quantity of alcohol, ester and water products will continue to increase the amount of sulfuric acid vapor, measures to balance the right move. The characteristics of this reaction: (1) high reaction temperature, equilibrium time is short; (2) simple operation; (3) a higher conversion rate. Five, experimental steps: Adding 95% 8ml in dry 100ml three necked flask ethanol in cold water cooling, shaking while slowly adding 8ml concentrated sulfuric acid (questions 1, 2) (question 3) zeolite; adding 8ml 95% in the dropping funnel of ethanol and 8ml acetic acid, shake (question 4). According to the book arrangement of assembl