海藻酸纤维对Pb2的吸附动力学及吸附平衡研究.DOCVIP

海藻酸纤维对Pb2+的吸附动力学及吸附平衡研究 张笑雪：2012214086 赵双红：2012214087 赵旭：2012214088 陈 曦： 2012214091 许时颖：2012214075 赵澈：2512214017 摘要 本文以海藻酸纤维作为吸附材料研究了其对Pb2+的吸附性能，用准一级动力学方程、准二级动力学方程、Elovich 方程、双常数方程和指数函数方程数学模型对不同Pb2+吸附时间的吸附曲线进行分析, 研究了其吸附的动力学机理。并且用Langmuir、Freundlich、Temkin方程，研究了其平衡吸附机理。结果表明：在所研究的条件下，准二级动力学模型的拟合度较好，模拟值与实验值较吻合，说明海藻酸纤维对Pb2+的吸附是化学吸附过程；Langmuir和Freundlich方程可较好的模拟海藻酸纤维对Pb2+的吸附平衡，且海藻酸纤维对Pb2+的吸附是单分子吸附。 关键词：海藻酸纤维 吸附 Pb2+ 动力学 吸附平衡 Abstract This study mainly investigated heavy metal ions(Pd2+)adsorption of alginate acid fiber as a biosorbent．At the same time，pseudo-first—order, Pseudo-second-order kinetic model, Elovich equation , Two-constant equation, Exponential function equation were used to describe the adsorption of Pb2+, and studied the adsorption dynamics mechanism. At the same time through Langmuir, Freundlich, Temkin equation, the equilibrium adsorption mechanism is studied. The Results show that in the study conditions, Pseudo-second-order kinetic model were applied to simulate the experimental parameters．simulation value with the theoretical results fit well with the experimental value, showed the alginate fibers to the adsorption of Pb2 + is a chemical adsorption process; Langmuir and Freundlich equation can better simulate alginate fibers for the adsorption of Pb2+ balance, and the alginate fiber is single molecular adsorption to the adsorption of Pb2+. chemisorptions is the main reaction step throughout the adsorption process．Adsorption behavior of Pb2 + can be approximately described with the Langmuir and Freundlich equations and it was regarded as monolayer biosorption．adsorption equilibrium 为了开发环保、高效、无二次污染的重金属废水治理方法，生物吸附技术在环境领域得到越来越多的关注，也成为了近几年来迅速发展的新兴技术。生物吸附技术是指利用廉价的生物细胞体吸附重金属离子，从而达到去除水体中有害重金属离子的目的[1]。它具有吸附剂来源广、处理效率高、投资成本少、易于回收重金属等特点[2]。 海藻酸是从褐藻（海带、巨藻、裙带菜等）中提取出的一种多糖，是水溶性的天然高分子材料。它由α-L-古罗糖醛酸（G）和β-D-甘露糖醛酸（M）组成的一种无规线性嵌段共聚物，其中G是M在C-5位的立体异构体。由图1可知，海藻酸中含有大量的羧基基团，它可以与各种金属离子结合成盐，如水溶性的海藻酸钠、海藻酸钾等以及不溶于水的海藻酸钙[3]。由于它对金属离子具有不同的结合力，有研究表明[4]，海藻酸结合