聚乙烯合胶之流动行为的探讨.PDFVIP

聚乙烯合膠之流動行為的探討 劉俊良 郭建麟 許建彬 陳恕勛 張建凱 羅棨中 國立宜蘭技術學院化學工程系 摘 要 本專題計畫將二不同結構的聚乙烯混合形成合膠(Blend)來探討混摻比率(Blending ratio)對聚乙烯流動行 為的影響。所使用的樣品分別為一傳統製程製造的低密度聚乙烯(LDPE)及以metallocene 觸媒製造聚乙烯 (mPE) ；其中後者為不結晶的熱塑性彈性體。所採用之樣品中除了兩個純料外，合膠的混合比率分別為 1:3 、1:1 及3:1 三種，故有五種不同比例之受測樣品。流動行為之探討以Keyness Galaxy III 毛細管流變儀 行之。測試過程中使用了三種不同長度/直徑(L/D)比之毛細管模頭(Die) ；分別為16 、20 及30 。毛細管模頭 之直徑為1.0 mm 。測試的溫度為200℃、220℃及240℃。結果顯示五不同樣品所測得之黏度隨著樣品中 mPE 的含量增加而上升；且不按合膠比率呈系統性分佈。此一現象可用Arrehenius 方程式＝A 中的 常數來合理化。此外，五種樣品的流動活化能在測試範圍內，除了LDPE 較大外，其餘四種樣品的流動活 化能在實驗誤差範圍內，可視為相同。這歸因於LDPE 具有較廣泛之纏結所致。 關鍵詞 ：LDPE 、mPE 、混摻比率、流動行為、毛細管流變儀、Arrehenius 方程式 Flow Behavior of Polyethylene Blends Jung-Liang Liu Jian-Lin Kuo Jian-Bin She Su-Shen Chen Jian-Kiy Chang Chi-Chung Luo Department of Chemical Engineering, National Ilan Institute of Technology Abstract Two different types of polyethylene were used to study the flow behavior of their blends. They were a traditional low density polyethylene (LDPE) and a metallocene polyethylene (mPE); the latter is a thermoplastic elastomer polyethylene and is non-crystallizable. Blends were prepared in three different ratios, 1:3, 1:1 and 3:1, respectively. Including two counterparts, five samples were used in this study. The flow behavior of the samples was examined via a Kayness Galaxy III capillary rheometer. Three different dies were used. All have the same diameter, 1mm, but difference in L/D (length/diameter) ratio. They were 16, 20, and 30. Flow behavior was also examined with three different temperature, 200C, 220C and 240C, respectively. Results showed that the viscosities of the samples increase with mPE content. However, the flow curves of blends did not distribute systematically with respect to blending r