new polyhydroxylated furostanol saponins with inhibitory action against no production from tupistra chinensis rhizomes新polyhydroxylated furostanol皂苷抑制行动没有生产从tupistra红豆杉的根状茎.pdfVIP

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new polyhydroxylated furostanol saponins with inhibitory action against no production from tupistra chinensis rhizomes新polyhydroxylated furostanol皂苷抑制行动没有生产从tupistra红豆杉的根状茎.pdf

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new polyhydroxylated furostanol saponins with inhibitory action against no production from tupistra chinensis rhizomes新polyhydroxylated furostanol皂苷抑制行动没有生产从tupistra红豆杉的根状茎

Molecules 2007, 12, 2029-2037 molecules ISSN 1420-3049 © 2007 by MDPI /molecules Full Paper New Polyhydroxylated Furostanol Saponins with Inhibitory Action against NO Production from Tupistra chinensis Rhizomes Lan-Lan Xu 1, Kun Zou 1,*, Jun-Zhi Wang 1, Jun Wu 2, Yuan Zhou 1, Fei-Jun Dan 1 and Jing 1 Yang 1 Hubei Key Laboratory of Natural Products Research and Development, College of Chemistry and Life Science, China Three Gorges University, Yichang 443002, P.R. China; E-mails: llxu@ (Lan-Lan Xu), horsedog@163.com (Jun-Zhi Wang), yuanzhou@, fjdan@ (Fei-Jun Dan), jyang@ (Jing Yang) 2 Guangdong Key Laboratory of Marine Materia Medica, South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510301, P.R. China; E-mail: wwujun68@163.com * Author to whom correspondence should be addressed; E-mail: kzou@; Tel: (+86)-717- 6392286/Fax: (+86)-717-6397478 Received: 8 June 2007; in revised form: 11 July 2007 / Accepted: 12 July 2007 / Published: 23 August 2007 Abstract: Two furostanol saponins were obtained from the rhizomes of Tupistra chinensis 25(27) Bak. Their structures were determined as 5β-furost-Δ -en-1β,2β,3β,4β,5β,7α,22ξ,26- octaol-6-one-26-O-β-D-glucopyranoside (1) and 5β-furost-Δ25(27)-en-1β,2β,3β,4β,5β,6β, 7α,22ξ,26-nonaol-26-O-β-D-glucopyranoside (2), on the basis of chemical and spectroscopic evidence. Both compounds displayed marked inhibitory action against NO production in rat abdomen macrophages induced