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n-salicylideneamine derivatives with tempo substituentsn-salicylideneamine衍生品取代基与节奏
Molecules 2004, 9, 746-756
molecules
ISSN 1420-3049
N-Salicylideneamine Derivatives with TEMPO Substituents
Masayuki Hata, Hiroki Akutsu, Jun-ichi Yamada and Shin’ichi Nakatsuji*
Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297,
Japan. Tel.: (+81)-791-58-0163, Fax: (+81)-791-58-0164.
* Author to whom correspondence should be addressed; e-mail: nakatuji@sci.u-hyogo.ac.jp.
Received: 25 April 2004 / Accepted: 21 May 2004 / Published: 31 August 2004
Abstract: Three N-salicylideneamine derivatives bearing TEMPO (2,2,6,6-tetra-
methyl-1-piperidinyloxy) substituents were prepared in order to study their structure and
property relationships and to investigate the possibilities of the existence of heat and/or
light responsive magnetic properties. Curie-Weiss behavior with weak ferromagnetic
intermolecular spin-spin interactions was observed in one of the radicals, while
antiferromagnetic interactions were predominant for the other radicals and the
structure-property relationships were investigated for the radical compounds from their
crystal structures obtained by X-ray analyses. Preliminary results of the examination of
their responses towards light and heat are also described.
Keywords: Salicylideneamine, salicylideneaniline, TEMPO, magnetic property, crystal
structure
Introduction
Considerable attention is now focused on the development of organic and molecular-based magnetic
materials and a number of new spin systems have been prepared
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