phosphotungstic acid an efficient, cost-effective and recyclable catalyst for the synthesis of polysubstituted quinolines磷钨酸高效、成本效益和可回收的催化剂的合成为喹啉类药物.pdfVIP

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phosphotungstic acid an efficient, cost-effective and recyclable catalyst for the synthesis of polysubstituted quinolines磷钨酸高效、成本效益和可回收的催化剂的合成为喹啉类药物.pdf

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phosphotungstic acid an efficient, cost-effective and recyclable catalyst for the synthesis of polysubstituted quinolines磷钨酸高效、成本效益和可回收的催化剂的合成为喹啉类药物

Molecules 2009, 14, 1126-1133; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Communication Phosphotungstic Acid: An Efficient, Cost-effective and Recyclable Catalyst for the Synthesis of Polysubstituted Quinolines Minoo Dabiri 1,* and Sahareh Bashiribod 2 1 Department of Chemistry, Faculty of Science, Shahid Beheshti University, G. C., Evin 1983963113, Tehran, Iran 2 Department of Marine Biology, Faculty of Biological Scinences Shahid Beheshti University, G. C., Evin, Tehran, Iran * Author to whom correspondence should be addressed; E-mail: m-dabiri@sbu.ac.ir. Received: 4 January 2009; in revised form: 20 January 2009 / Accepted: 17 February 2009 / Published: 12 March 2009 Abstract: Phosphotungstic acid (H3PW12O40) was used as an efficient and recyclable catalyst for the synthesis of polysubstituted quinolines through the Friedländer condensation of 2-aminoarylketone with carbonyl compounds, which was achieved by conventional heating under solvent-free conditions. Keywords: Heteropolyacid; Heterogeneous catalysis; Friedländer annelation; Quinoline. Introduction Over the past 20 years, the chemistry community, and in particular, the chemical industry, has made extensive efforts to reduce the risks associated with the manufacture and use of various chemicals. Green chemistry is an approach to the synthesis, processing, and use of chemicals that aims to reduce the risks to humans and the environment. Much innovative chemistry