photomechanical response of composite structures built from azobenzene liquid crystal polymer networks照相制版工艺的反应复合结构由偶氮苯液晶聚合物网络.pdfVIP

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photomechanical response of composite structures built from azobenzene liquid crystal polymer networks照相制版工艺的反应复合结构由偶氮苯液晶聚合物网络.pdf

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photomechanical response of composite structures built from azobenzene liquid crystal polymer networks照相制版工艺的反应复合结构由偶氮苯液晶聚合物网络

Polymers 2011, 3, 1447-1457; doi:10.3390/polym3031447 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Photomechanical Response of Composite Structures Built from Azobenzene Liquid Crystal Polymer Networks Kyung Min Lee 1,2 and Timothy J. White 1,* 1 Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright Patterson Air Force Base, OH 45433, USA; E-Mail: kyungmin.lee@ 2 Azimuth Corporation, Dayton, OH 45433, USA * Author to whom correspondence should be addressed; E-Mail: timothy.white2@; Tel.: +1-937-255-9551; Fax: +1-937-255-11-282. Received: 1 August 2011; in revised form: 19 August 2011 / Accepted: 30 August 2011 / Published: 2 September 2011 Abstract: Optically directed shape adaptive responses have been sought after for many decades in photoresponsive polymeric materials. A number of recent examinations have elucidated elucidated the unique opportunities of photomechanical responses realized in azobenzene-functionalized liquid crystalline polymer networks (both elastomers and glasses). This work summarizes and contrasts the photomechanical response of glassy polydomain, monodomain, and twisted nematic azo-LCN materials to blue-green irradiation. Building from this summary, the combinatorial photomechanical response observed upon irradiation of composite cantilevers is examined. Large scale shape adaptations are realize