原创力文档relative stereochemistry of a diterpene from salvia cinnabarina相对立体化学的二萜鼠尾草cinnabarina.pdfVIP
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relative stereochemistry of a diterpene from salvia cinnabarina相对立体化学的二萜鼠尾草cinnabarina
Molecules 2007, 12, 2279-2287
molecules
ISSN 1420-3049
© 2007 by MDPI
/molecules
Full Paper
Relative Stereochemistry of a Diterpene from Salvia cinnabarina
1 2 3 3 2
Angela Bisio , Bruno Pagano , Alessia Romussi , Olga Bruno , Nunziatina De Tommasi ,
Giovanni Romussi 1 and Carlo Andrea Mattia 2,*
1 Dipartimento di Chimica e Tecnologie Farmaceutiche e Alimentari, Università di Genova, Via
Brigata Salerno, Genova, Italy
2 Dipartimento di Scienze Farmaceutiche, Università di Salerno, Via Ponte Don Melillo, 84084
Fisciano, Salerno, Italy
3 Dipartimento di Scienze Farmaceutiche, Università di Genova, Viale Benedetto XV, Genova, Italy
* Author to whom correspondence should be addressed. E-mail: mattia@unisa.it
Tel.: +39 089 969759, Fax: +39 089 969602
Received: 27 September 2007; in revised form: 5 October 2007 / Accepted: 5 October 2007 /
Published: 9 October 2007
Abstract: The relative stereochemistry of 3,4-secoisopimara-4(18),7,15-triene-3-oic acid,
a diterpenoid with antispasmodic, hypotensive and antibacterial activities isolated from
Salvia cinnabarina, was determined by an X-ray diffraction analysis of a single crystal of a
suitable crystalline derivative.
Keywords: Salvia cinnabarina, Lamiaceae, secoisopimarane-diterpene, relative stereo-
chemistry, X-ray structure.
Introduction
The genus Salvia (family Lamiaceae) includes over 900 species growi
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