reversible low-light induced photoswitching of crowned spiropyran-do3a complexed with gadolinium(iii) ions可逆的光线感应光电开关的加冕spiropyran-do3a包裹着钆离子(iii).pdfVIP

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reversible low-light induced photoswitching of crowned spiropyran-do3a complexed with gadolinium(iii) ions可逆的光线感应光电开关的加冕spiropyran-do3a包裹着钆离子(iii).pdf

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reversible low-light induced photoswitching of crowned spiropyran-do3a complexed with gadolinium(iii) ions可逆的光线感应光电开关的加冕spiropyran-do3a包裹着钆离子(iii)

Molecules 2012, 17, 6605-6624; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Reversible Low-Light Induced Photoswitching of Crowned Spiropyran-DO3A Complexed with Gadolinium(III) Ions 1 2 3 1 Klaus Kruttwig , Diego R. Yankelevich , Chantal Brueggemann , Chuqiao Tu , Noelle L’Etoile 3, André Knoesen 2 and Angelique Y. Louie 1,* 1 Department of Biomedical Engineering, University of California, Davis, CA 95616, USA 2 Department of Electrical and Computer Engineering, University of California, Davis, CA 95616, USA 3 Department of Cell and Tissue Biology, University of California, San Francisco, CA 94143, USA * Author to whom correspondence should be addressed; E-Mail: aylouie@; Tel.: +1-530-752-7134; Fax: +1-530-752-5739. Received: 26 March 2012; in revised form: 11 May 2012 / Accepted: 25 May 2012 / Published: 31 May 2012 Abstract: Photoswitchable spiropyran has been conjugated to the crowned ring system DO3A, which improves its solubility in dipolar and polar media and stabilizes the merocyanine isomer. Adding the lanthanide ion gadolinium(III) to the macrocyclic ring system leads to a photoresponsive magnetic resonance imaging contrast agent that displays an increased spin-lattice relaxation time (T ) upon visible light stimulation. In this work, 1 the photo