richness of side-chain liquid-crystal polymers from isotropic phase towards the identification of neglected solid-like properties in liquids丰富的侧链液晶聚合物从各向同性相的识别被忽视的固体状的液体的性质.pdfVIP
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richness of side-chain liquid-crystal polymers from isotropic phase towards the identification of neglected solid-like properties in liquids丰富的侧链液晶聚合物从各向同性相的识别被忽视的固体状的液体的性质
Polymers 2012, 4, 1109-1124; doi:10.3390/polym4021109
OPEN ACCESS
polymers
ISSN 2073-4360
/journal/polymers
Article
Richness of Side-Chain Liquid-Crystal Polymers:
From Isotropic Phase towards the Identification of
Neglected Solid-Like Properties in Liquids
Laurence Noirez 1,*, Hakima Mendil-Jakani 1,2, Patrick Baroni 1 and Joachim H. Wendorff 3
1
Laboratoire Léon Brillouin (CEA-CNRS), CE-Saclay, Gif-sur-Yvette 91191, France;
E-Mails: hakima.mendil-jakani@cea.fr (H.M.-J.); patrick.baroni@cea.fr (P.B.)
2
Structure et Propriétés d’Architectures Moléculaires, UMR 5819 SPrAM (CEA-CNRS-UJF),
CEA-Grenoble, 17, avenue des Martyrs, Grenoble 38054, cedex 9, France
3 Fachbereich Chemie, Philipps-Universität Marburg, D-35032 Marburg, Germany;
E-Mail: wendorff@staff.uni-marburg.de
* Author to whom correspondence should be addressed; E-Mail: laurence.noirez@cea.fr;
Tel.: +33-1-6908-6300; Fax: +33-1-6908-8261.
Received: 6 March 2012; in revised form: 1 April 2012 / Accepted: 20 April 2012 /
Published: 25 April 2012
Abstract: Very few studies concern the isotropic phase of Side-Chain Liquid-Crystalline
Polymers (SCLCPs). However, the interest for the isotropic phase appears particularly
obvious in flow experiments. Unforeseen shear-induced nematic phases are revealed away
from the N-I transition temperature. The non-equilibrium nematic phase in the isotropic
phase of SCLCP melts challenges the conventional timescales described in theoretical
approaches and reveal very long t
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