selective preparation of furfural from xylose over sulfonic acid functionalized mesoporous sba-15 materials选择性制备糠醛从木糖磺酸功能化介孔sba-15材料.pdfVIP

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selective preparation of furfural from xylose over sulfonic acid functionalized mesoporous sba-15 materials选择性制备糠醛从木糖磺酸功能化介孔sba-15材料.pdf

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selective preparation of furfural from xylose over sulfonic acid functionalized mesoporous sba-15 materials选择性制备糠醛从木糖磺酸功能化介孔sba-15材料

Energies 2011, 4, 669-684; doi:10.3390/en4040669 OPEN ACCESS energies ISSN 1996-1073 /journal/energies Article Selective Preparation of Furfural from Xylose over Sulfonic Acid Functionalized Mesoporous Sba-15 Materials Xuejun Shi 1, Yulong Wu 1,*, Huaifeng Yi 2, Guo Rui 1, Panpan Li 1, Mingde Yang 1 and Gehua Wang 1,* 1 Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China; E-Mails: shxj@ (X.S.); ruiguoff@163.com (G.R.); 2005lipanpan@ (P.L.); yangmd@ (M.Y.) 2 Petrochina Xinjiang Oilfield Company, Karamay 834000, China; E-Mail: yhf@ * Authors to whom correspondence should be addressed; E-Mails: wylong@ (Y.W.); wanggehua@ (G.W.); Tel.: +86-10-8979-6086; Fax: +86-10-6977-1464. Received: 25 March 2011; in revised form: 11 April 2011 / Accepted: 18 April 2011 / Published: 20 April 2011 Abstract: Sulfonic acid functionalized mesoporous SBA-15 materials were prepared using the co-condensation and grafting methods, respectively, and their catalytic performance in the dehydration of xylose to furfural was examined. SBA-15-SO3H(C) prepared by the co-condensation method showed 92–95% xylose conversion and 74% furfural selectivity, and 68–70% furfural yield under the given reaction conditions. The deactivation and regeneration of the SBA-15-SO3H(C) catalyst for the dehydration of xylose was also investigated. The results indicate that the used and regeneration catalysts retained the SBA-15 mesoporous structure, and the S content of SBA