spectroscopy and speciation studies on the interactions of aluminum (iii) with ciprofloxacin and β-nicotinamide adenine dinucleotide phosphate in aqueous solutions光谱和物种形成的相互作用研究铝(iii)和环丙沙星β-nicotinamide腺嘌呤二核苷酸磷酸水溶液.pdfVIP

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spectroscopy and speciation studies on the interactions of aluminum (iii) with ciprofloxacin and β-nicotinamide adenine dinucleotide phosphate in aqueous solutions光谱和物种形成的相互作用研究铝(iii)和环丙沙星β-nicotinamide腺嘌呤二核苷酸磷酸水溶液.pdf

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spectroscopy and speciation studies on the interactions of aluminum (iii) with ciprofloxacin and β-nicotinamide adenine dinucleotide phosphate in aqueous solutions光谱和物种形成的相互作用研究铝(iii)和环丙沙星β-nicotinamide腺嘌呤二核苷酸磷酸水溶液

Molecules 2012, 17, 9379-9396; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Spectroscopy and Speciation Studies on the Interactions of Aluminum (III) with Ciprofloxacin and β-Nicotinamide Adenine Dinucleotide Phosphate in Aqueous Solutions Xiaoling Ma 1, Li Li 2, Chongzheng Xu 2, Haiyan Wei 2, Xianlong Wang 3,* and Xiaodi Yang 2,* 1 Nanjing Maternity and Child Health Care Hospital, Nanjing Medical University, Nanjing 210004, China 2 Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, China 3 Key Laboratory of NeuroInformation of the Ministry of Education, School of Life Science and Technology, University of Electronic Science and Technology of China, Chengdu 610054, China * Authors to whom correspondence should be addressed; E-Mails: chem.wang@ (X.W.); yangxiaodi@ (X.Y.); Tel.: +86-139-0821-5057 (X.W.); Tel.: +86-25-8359-8648 (X.Y.); Fax: +86-25-8589-1767 (X.Y.). Received: 2 July 2012; in revised form: 25 July 2012 / Accepted: 26 July 2012 / Published: 3 August 2012 Abstract: In this study, both experimental and theoretical approaches, including absorption spectra, fluorescence emission spectra, 1H- and 31P-NMR, electrospray ionization mass spectrometry (ESI-MS), pH-potentiometry and theoretical approaches using the BEST SPE computer programs were applied to study the competitive complexation between ciprofloxacin (CIP) and -nicotinamide adenine dinucleotide phos