study on exothermic oxidation of acrylonitrile-butadiene-styrene (abs) resin powder with application to abs processing safety研究氧化放热的丙烯腈-丁二烯-苯乙烯(abs)树脂粉末应用abs处理安全.pdfVIP

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study on exothermic oxidation of acrylonitrile-butadiene-styrene (abs) resin powder with application to abs processing safety研究氧化放热的丙烯腈-丁二烯-苯乙烯(abs)树脂粉末应用abs处理安全.pdf

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study on exothermic oxidation of acrylonitrile-butadiene-styrene (abs) resin powder with application to abs processing safety研究氧化放热的丙烯腈-丁二烯-苯乙烯(abs)树脂粉末应用abs处理安全

Polymers 2010, 2, 174-187; doi:10.3390/polym2030174 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Study on Exothermic Oxidation of Acrylonitrile-butadiene- styrene (ABS) Resin Powder with Application to ABS Processing Safety Yih-Shing Duh 1,*, Ta-Cheng Ho 2, Jenq-Renn Chen 3 and Chen-Shan Kao 4,* 1 Department of Occupational Safety and Health, Jen-Teh Junior Colledge of Medicine, Nursing and Management, Taiwan 2 Energy and Environment Research Laboratories, Industrial Research Technology Institute, Taiwan; E-Mail: tcho@.tw 3 Department of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, Taiwan; E-Mail: jrc@.tw 4 Department of Safety Health and Environmental Engineering, National United University, Miaoli, Taiwan * Author to whom correspondence should be addressed; E-Mails: yihshingduh@.tw (Y.S.D.); jcsk@.tw (C.S.K.). Received: 7 June 2010; in revised form: 16 July 2010 / Accepted: 2 August 2010 / Published: 4 August 2010 Abstract: Oxidative degradation of commercial grade ABS (Acrylonitrile-butadiene- styrene) resin powders was studied by thermal analysis. The instabilities of ABS containing different polybutadiene (PB) contents with respect to temperature were studied by Differential Scanning Calorimeter (DSC). Thermograms of isothermal test and dynamic scanning were performed. Three exothermic peaks were observed and related to auto-oxidation, degradation and oxidative decomposition, respectively. Onset