synthesis and crystal structure determination of a nickel(ii) complex of an acyclic pentadentate (n5) mono schiff base ligand合成和晶体结构测定镍(ii)复杂的非循环pentadentate mono席夫碱配体(它们).pdfVIP
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synthesis and crystal structure determination of a nickel(ii) complex of an acyclic pentadentate (n5) mono schiff base ligand合成和晶体结构测定镍(ii)复杂的非循环pentadentate mono席夫碱配体(它们)
Molecules 2001, 6, 909-914
molecules
ISSN 1420-3049
Synthesis and Crystal Structure Determination of a Nickel(II)
Complex of an Acyclic Pentadentate (N5) Mono Schiff Base
Ligand.
1, 1 2 2
Hassan Keypour *, Sadegh Salehzadeh , R. G. Pritchard and R. V. Parish
1 Department of Chemistry, Bu-Ali Sina University, Hamadan, Zip Code 65174, Iran.
2 Department of Chemistry, UMIST, PO Box 88, Manchester M60 1QD, UK.
* Author to whom correspondence should be addressed, Fax (+98) 811 8272404, e-mail:
keypour@basu.ac.ir
Received: 19 June 2001; in revised form 24 September 2001 / Accepted: 22 October 2001 /
Published: 31 October 2001
Abstract: The asymmetrical tripodal tetraamine ligand N[(CH ) NH ] [(CH ) NH ]
2 3 2 2 2 2 2
(ppe) was condensed with 2-acetylpyridine in the presence of nickel(II) ion. In ethanol-
water solution the reaction stops after the first stage of condensation, and a new nickel(II)
complex of an acyclic pentadentate (N5) mono Schiff base ligand was obtained. X-ray
structure analysis of the resulting complex, [Ni(ppe-py)(H O)](ClO ) , indicates that
2 4 2
condensation with 2-acetylpyridine is at the propylene chain of ppe. The geometry
around the nickel ion is distorted octahedra
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