synthesis and evaluation of a molecularly imprinted polymer for 2,4-dinitrophenol分子印迹聚合物的合成和评价2,4-dinitrophenol.pdfVIP
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synthesis and evaluation of a molecularly imprinted polymer for 2,4-dinitrophenol分子印迹聚合物的合成和评价2,4-dinitrophenol
Int. J. Mol. Sci. 2009, 10, 354-365; doi:10.3390/ijm
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/journal/ijms
Article
Synthesis and Evaluation of a Molecularly Imprinted Polymer
for 2,4-Dinitrophenol
Nor Dyana Zakaria, Nor Azah Yusof *, Jelas Haron and Abdul Halim Abdullah
Chemistry Department, Faculty of Science, University Putra Malaysia, 43400, Serdang, Selangor,
Malaysia. E-Mails: myaminx@ (N. Z.); halim@.my (A. A.);
mdjelas@.my (J. H.)
* Author to whom correspondence should be addressed; E-Mail: azah@.my;
Tel. +603 Fax: +603
Received: 13 October 2008; in revised form: 19 December 2008 / Accepted: 7 January 2009 /
Published: 22 January 2009
Abstract: Molecular imprinted polymers (MIP) are considered one of the most
promising selective and novel separation methods for removal phenolic compound in
wastewater treatment. MIP are crosslinked polymeric materials that exhibit high binding
capacity and selectivity towards a target molecule (template), purposely present during
the synthesis process. In this work MIP were prepared in a bulk polymerization method
in acetonitrile using 2,4-dinitrophenol, acrylamide, ethylene glycol dimethacrylate, and
benzoyl peroxide as template, functional monomer, cross-linker and initiator,
respectively. An adsorption process for removal of nitrophenol using
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