原创力文档synthesis and crystal structure of a new triosmium alkylidyne carbonyl cluster containing a chiral ferrocenylphosphine ligand羰基合成和晶体结构的新triosmium alkylidyne集群含有一个手性ferrocenylphosphine配体.pdfVIP
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synthesis and crystal structure of a new triosmium alkylidyne carbonyl cluster containing a chiral ferrocenylphosphine ligand羰基合成和晶体结构的新triosmium alkylidyne集群含有一个手性ferrocenylphosphine配体
Molecules 2005, 10, 640-648
molecules
ISSN 1420-3049
Synthesis and Crystal Structure of a New Triosmium Alkylidyne
Carbonyl Cluster Containing a Chiral Ferrocenylphosphine
Ligand
Wai-Yeung Wong *
Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong,
P.R. China. Tel. (+84) 852-3411-7074, Fax: (+84) 852-3411-7348
* Author to whom correspondence should be addressed; e-mail: rwywong@.hk
Received: 13 July 2004 / Accepted: 03 September 2004 / Published: 14 July 2005
Abstract: The synthesis, spectroscopic characterization and X-ray crystal structure of a new
5
chiral triosmium alkylidyne carbonyl cluster, (R,S)-[Os (µ-H) (CO) {µ -CPPh (η -
3 2 9 3 2
5
C H )Fe(η -C H (PPh )CH(Me)NMe )}] (1) are described. Compound 1 crystallizes in the
5 4 5 3 2 2
non-centrosymmetric space group P2 and its absolute configuration has been established.
1
The structure consists of an Os3C metal core with one of the PPh2 moieties of the chiral
ferrocenylphosphine bonded to the apical alkylidyne carbon atom to give a zwitterionic
cluster complex, reminiscent of the phosphorus ylide.
Keywords: Alkylidyne, Chirality, Ferrocene, Metal Cluster, Osmium.
Introduction
A non-centrosymmetric crystal packing of molecules i
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