synthesis and spectral evaluation of some unsymmetrical mesoporphyrinic complexes一些不对称合成和光谱评价mesoporphyrinic复合物.pdfVIP

Int. J. Mol. Sci. 2012, 13, 8112-8125; doi:10.3390/ijm OPEN ACCESS International Journal of Molecular Sciences ISSN 1422-0067 /journal/ijms Article Synthesis and Spectral Evaluation of Some Unsymmetrical Mesoporphyrinic Complexes Rica Boscencu 1,*, Anabela Sousa Oliveira 2,3, Diana P. Ferreira 2 and Luís Filipe Vieira Ferreira 2 1 Faculty of Pharmacy, “Carol Davila” University of Medicine and Pharmacy, 6 Traian Vuia St., Bucharest 020956, Romania 2 Molecular Physical Chemistry Center, IN—Institute of Nanoscience and Nanotechnology, Technical University of Lisbon, Av. Rovisco Pais, Lisbon 1049-001, Portugal; E-Mails: asoliveira@estgp.pt (A.S.O.); diana.ferreira@ist.utl.pt (D.P.F.); luisfilipevf@ist.utl.pt (L.F.V.F.) 3 School of Technology and Business, Polytechnic Institute of Portalegre, Lugar da Abadessa, Apartado 148, Portalegre 7301-901, Portugal * Author to whom correspondence should be addressed; E-Mail: rboscencu@; Tel./Fax: +4021-3111152. Received: 15 February 2012; in revised form: 13 June 2012 / Accepted: 21 June 2012 / Published: 29 June 2012 Abstract: Synthesis and spectral evaluation of new zinc and copper unsymmetrical mesoporphyrinic complexes are reported. Zn(II)-5-(4-acetoxy-3-methoxyphenyl)-10,15,20- tris-(4-carboxymethylphenyl)porphyrin, Zn(II)-5-[(3,4-methylenedioxy)phenyl]-10,15,20- tris-(4-carboxymethylphenyl)porphyrin, Cu(II)-5-(4-acetoxy-3-methoxyphenyl)-10,15,20- tris-(4-carboxymethylphenyl)porphyrin and Cu(II)-5-