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terpenoids and bibenzyls from three argentine liverworts萜类化合物和bibenzyls从三个阿根廷苔类
Molecules 2011, 16, 10471-10478; doi:10.3390/molecules161210471
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Terpenoids and Bibenzyls from Three Argentine Liverworts
Fumihiro Nagashima * and Yoshinori Asakawa
Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho,
Tokushima 770-8514, Japan; E-Mail: asakawa@ph.bunri-u.ac.jp (Y.A.)
* Author to whom correspondence should be addressed; E-Mail: fnaga@ph.bunri-u.ac.jp;
Tel.: +81-88-602-8450; Fax: +81-88-655-3051.
Received: 22 November 2011; in revised form: 5 December 2011 / Accepted: 12 December 2011 /
Published: 16 December 2011
Abstract: A new rosane diterpenoid, 3-hydroxy-5,15-rosadien-11-one (3), was isolated,
together with a known rosane diterpenoid, 5,15-rosadiene-3,11-dione (4), and an
aromadendrane sesquiterpenoid, ent-cyclocolorenone (5), from the Et O extract of an
2
unidentified Argentine liverwort Anastrophyllum species. Moreover, four known
sesquiterpene lactones 6–9 and two known bibenzyls 10, 11 were isolated from the Et O
2
extracts of Argentine Frullania brasiliensis and Radula voluta, respectively. The structures
of compounds 3–11 were determined by the use of NMR techniques.
Keywords: Jungermanniales; liverwort; Radula voluta ; Fr
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