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考点1.氧化还原反应及其配平(Oxidation reduction reaction and its balance at test site 1.)
考点1.氧化还原反应及其配平(Oxidation reduction reaction and its balance at test site 1.)
Oxidation reduction reaction and its balance at test site 1.
1., review the key points: 1, the concept of redox reaction.
2. Application of electron conservation principle.
3, according to the valence number conservation chemical reaction equation.
2. difficulties focus
Concepts and regularities in redox reactions:
One, five pairs of concepts
In redox reactions, there are five opposing and related concepts. Their names and relationships are:
Two, five rules
1, the nature of the law of performance
The same element has a variety of valence, generally at the highest valence only with oxidation, the lowest valence only with reduction, in the middle can not only has the oxidation resistance and constant reducibility.
2, the nature of the law of strength
3, the law of reaction
The concentration of similar, and contains several of the reductant, adding the oxidant, it is the first and strongest reductant solution; similarly, the difference in the concentration of the solution, also contains several oxidants, adding reducing agent, it is the first and strongest oxidation solution agent. For example, by entering Cl2 into a solution containing FeBr2, the Fe2+ is first oxidized
4, the regularity of valence
When the redox reaction occurs between the substances with different valence states, the change of the valence state of the element must follow the law of high price + low price to intermediate price.
5. Electron conservation law
In any redox reaction, the total number of electrons obtained by an oxidant (or sharing of electrons) is equal to the total number of electrons in the reductant (or the deviation of the common electron pair).
Three. Comparison of the strength or reducibility of substances:
(1) comparison of metals or nonmetals of elements
The oxidation of 1 cations decreases with the increase of their reducibility
The reducibility of the nonmetal anion decreases with the increase of the oxi
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