基于CMIA-Cd构建的MOF孔材料的溶剂热合成.PDF

Advances in Analytical Chemistry 分析化学进展, 2017, 7(3), 196-202 Published Online August 2017 in Hans. /journal/aac /10.12677/aac.2017.73025 The Hydrothermal Synthesis of Porous Material MOF Based on the CMIA-Cd Chen Feng, Ning Zhang, Liying Fu, Zhendong Feng, Fengchun Wang* Faculty of Chemistry, Tonghua Normal University, Tonghua Jilin th th th Received: Jul. 30 , 2017; accepted: Aug. 16 , 2017; published: Aug. 24 , 2017 Abstract In this paper, pyridine carboxylic acid ligands CMIA and transition meta Cd, thermal reaction with a solvent were used to build a new stable three-dimensional pore MOF materials. Structural analy- sis shows that the compound belongs to the monoclinic system, space group are P21/n, a = 8.1153(4) Å, b = 22.3470(9) Å, c = 25.348(3) Å, α = 90˚, β = 99.4500(10)˚, γ = 90˚, V = 3151.4(2) Å3, and IR analy- sis was used to explore the MOFs interaction and stability. Keywords CMIA Ligands, Cadmium Complexes, Transition Metal-Organic Frameworks 基于CMIA-Cd构建的MOF孔材料的溶剂热合 成 冯 晨，张 宁，付丽影，冯振东，王凤春* 通化师范学院，化学学院，吉林 通化 收稿日期：2017年7月30 日；录用日期：2017年8月16 日；发布日期：2017年8月24 日 摘 要 本论文利用羧酸类配体CMIA和Cd，利用溶剂热反应，构筑了一个新的稳定的三维MOF孔道材料。结构 分析表明该配合物属单斜晶系，空间群均为P21/n，a = 8.1153(4) Å，b = 22.3470(9) Å，c = 25.348(3) Å 3 ；α = 90˚，β = 99.4500(10)˚，γ = 90˚，V = 3151.4(2) Å ，并利用红外分析探讨了框架的相互作用。 *通讯作者。 文章引用: 冯晨, 张宁, 付丽影, 冯振东, 王凤春. 基于CMIA-Cd 构建的MOF 孔材料的溶剂热合成[J]. 分析化学进展, 2017, 7(3): 196-202. DOI: /10.12677/aac.2017.73025 冯晨 等 关键词 CMIA配体，镉配合物，金属–有机框架 Copyright © 2017 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International L