硫氰酸盐法测定痫复康中朱砂含量（Determination of cinnabar in Fu Fu Kang by thiocyanate method）.doc

硫氰酸盐法测定痫复康中朱砂含量（Determination of cinnabar in Fu Fu Kang by thiocyanate method） Determination of cinnabar in Fu Fu Kang by thiocyanate method Update Date: 2011-03-07 Click: Lv Feng, Xiao Minghu Abstract a thiocyanate method of xianfukang finished military general hospital preparation room and related simulation in the prescription of cinnabar were determined, and provide the basis for a reasonable amount of cinnabar in the party; experiments show that the method is simple, stable and reliable. The recovery rate was (98 + 1)%, and the coefficient of variation was less than 2%. Keywords thiocyanate method; xianfukang; cinnabar; mercuric sulfide Xianfukang by bezoar, cinnabar, pearl powder, turmeric and other traditional Chinese medicine composition has the efficacy of relieving convulsion, detoxification of Qingxin Anshen, by the Wuhan military general hospital for long-term clinical has obvious therapeutic effect in treating epilepsy. In view of the fact that cinnabar is the main active ingredient and the toxic component in it, it is easy for the patient to take the poisoning reaction for long time, so it is necessary to control the content of the substance. Chinese Pharmacopoeia (1995 1 edition) in the determination of mercuric sulfide cinnabar is a thiocyanate method, which contained most of the traditional Chinese medicine to the determination of cinnabar has not yet specified. In this paper, the content of cinnabar in Fu Fu Kang was determined by thiocyanate method. 1 experimental materials and reagents 1.1 cinnabar (purchased from Wuhan City Jiangan District medicine company), 1% Potassium Permanganate 2% solution of ferrous sulfate, ammonium ferric sulfate solution. 1.2 0.1 mol/L ammonium thiocyanate titration solution preparation: ammonium thiocyanate dissolved into water 0.76 g, 1000 ml, and precise amount of silver nitrate titration solution (0.1 mol/L) 25 ml, 50 ml water, 2 ml nitric acid and sulfuric acid iron indicator solution 2 ml, with ammonium thiocyan