气相色谱一质谱联用法测定聚氯乙烯塑料中 7种增塑剂（Determination of 7 plasticizers in polyvinyl chloride plastics by gas chromatography mass spectrometry）.docVIP

气相色谱一质谱联用法测定聚氯乙烯塑料中 7种增塑剂（Determination of 7 plasticizers in polyvinyl chloride plastics by gas chromatography mass spectrometry） Determination of 7 plasticizers in polyvinyl chloride plastics by gas chromatography mass spectrometry Li Ying, Liu Li, Wu Jingwu, Liu Zhihong, Jeky, Zhang Shen, Zhang Weiya (Shenzhen entry exit inspection and Quarantine Bureau, Shenzhen 518045) Abstract: a simple, rapid and accurate method for the determination of phthalic acid, two formic acid plasticizer in polyvinyl chloride (PVC) plastic products was developed. In PVC plastic products, 7 kinds of phthalate two formic acid vinegar plasticizers can be extracted effectively by ultrasonic assisted extraction in chloroform solvent, and then determined by gas chromatography mass spectrometry. The average recovery rate of the method is between 93.08% and 104, 1%, and the detection limit (s/N- 3) is between 0.05 10.0mg L 1, and the relative standard deviation is 0.5%. 5.4%. Keywords: gas chromatography-mass spectrometry; PVC plastics; plasticizers Polyvinyl chloride (PVC) is a kind of highly polar polymer molecules, there is a great force, which makes PVC plastic products become hard, lack of flexibility and flexibility, the effect of plasticizers is weaken the intermolecular forces, so as to improve the processability and flexibility of polymer [lj. Phthalate two formic acid vinegar is widely used as a plasticizer in PVC plastic products. The toxicology and biological toxicology and Environmental Monitoring Committee in the laboratory was found in the adjacent benzene two formic acid two isononanoic vinegar (DINP) have side effects on the liver and kidney, adjacent benzene two formic acid two (2 ethylhexyl) vinegar (DEHP) will damage the cardiovascular. Because plasticizers are not closely bound up with PVC molecules. As a result, plasticizers in PVC plastic products are likely to migrate more easily to sweat, saliva, and blood and liquids, causing harm to the human body. The EU has imposed